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膜分离 6

渗透汽化 5

绿色化工 4

反渗透 3

纳滤 3

聚偏氟乙烯 3

双极板 2

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水处理 2

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Hydrophilic modification of poly(aryl sulfone) membrane materials toward highly-efficient environmental

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 614-633 doi: 10.1007/s11705-021-2115-1

摘要: Poly(aryl sulfone) as a typical membrane material has been widely used due to excellent mechanical, chemical and thermal stability. However, the inherent hydrophobicity of poly(aryl sulfone) based membranes bears with the fouling issue during applications, which makes the membrane tending to adsorb contaminants on the surface so as to result in decreased separation performance and lifetime. In this critical review, we give a comprehensive overview on characterizations of hydrophilic membrane and diverse hydrophilic modification approaches of poly(aryl sulfone) membranes, predominantly including bulky, blending and surface modification technology. The discussions on the different modification methods have been provided in-depth. Besides, focusing on modification methods and performance of modified membranes, the related mechanisms for the performance enhancement are discussed too. At last, the perspectives are provided to guide the future directions to develop novel technology to manipulate the hydrophilicity of poly(aryl sulfone) membranes toward diverse practical and multi-functional applications.

关键词: poly(aryl sulfone)     membrane separations     modification     hydrophilicity     water treatment    

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

《环境科学与工程前沿(英文)》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1165-9

摘要:

A novel nanocomposite OMWCNT-A-GO was synthesized by conjugating OMWCNT and GO.

The P-OMWCNT-A-GO membrane was fabricated by non-solvent induced phase inversion.

The P-OMWCNT-A-GO exhibits the best water flux, BSA rejection and flux recovery.

It should be due to the enhanced membrane pore size, porosity and hydrophilicity.

关键词: carbon nanotubes     graphene oxide     mixed matrix membrane     nanohybrid     antifouling membrane     membrane hydrophilicity    

氯化水与地表水导致的膜污染对比解析——生物污染特性和微生物探究 Article

张莉, 徐磊, Nigel Graham, 俞文正

《工程(英文)》 2022年 第15卷 第8期   页码 154-164 doi: 10.1016/j.eng.2021.03.016

摘要:

氯在城市水处理过程中通常用于灭活病原体和预防水媒疾病,但是目前尚不清楚其作为一种预处理技术是否能够有效地缓解超滤过程中产生的膜污染。在本研究中,我们探究了自来水在重力驱动膜过滤系统中对生物膜的形成及生物污染的影响。同时,未处理的地表水(湖水)所形成的生物膜/生物污染也进行了对比研究。研究表明,自来水过滤系统产生了比湖水更严重的膜污染,而且多糖和eDNA的含量更高。其生物膜形态致密,但是湖水形成的生物膜是多孔、类似蜘蛛网状的结构,猜测可能与生物膜中的细菌有关。16S rRNA测序结果表明,Xanthobacter在自来水形成的生物膜中占据优势地位。此外,研究发现膜的亲、疏水性对膜污染特性和微生物群落的影响较小。本研究揭示了耐氯细菌在膜污染形成中的重要作用,更深入地认识了膜污染,可为寻求有效的膜污染控制方法提供帮助。

关键词: 膜污染     生物膜     GDM过滤技术     超滤     耐氯细菌     亲水性    

两亲高分子对超微滤膜的高性能化改性及应用

朱宝库,崔月,王俊,王纳川,姚之侃,朱利平

《中国工程科学》 2014年 第16卷 第12期   页码 87-93

摘要:

为提高分子超微滤膜材料的亲水性、抗污染性能、通量和寿命,降低膜材料制造成本,提出两亲高分子共混改性聚偏氟乙烯、聚氯乙烯、聚醚砜膜材料的基础与应用技术研究。研究中,从分子结构设计出发,采用多种活性聚合法合成了一系列具有不同组成和序列结构的两亲高分子,研究了不同组成与序列结构的两亲高分子在成膜过程中的表面富集的规律、两亲高分子在共混膜中的稳定化机制等基础问题;从成膜热力学和动力学出发实现了共混膜多层次微结构的调控,开发出多种两亲高分子合成及其共混超滤膜制备的技术,实现了膜材料规模化生产及其在自来水净化、废水处理及医疗过滤等领域的应用。

关键词: 两亲高分子     共混微孔膜     表面富集     亲水     抗污染    

Experimental investigations of frost release by hydrophilic surfaces

Zhongliang LIU, Lingyan HUANG, Yujun GOU, Yaomin LIU

《能源前沿(英文)》 2010年 第4卷 第4期   页码 475-487 doi: 10.1007/s11708-010-0114-x

摘要: Frost formation occurs when water vapor in the surrounding air comes into contact with cold surfaces through heat and mass transfer. It is usually an undesirable phenomenon in most refrigeration and cryogenic systems. A few studies have shown that changing the surface energy, such as increasing the surface hydrophilicity or hydrophobicity, has significant effects on frost growth. In this paper, a kind of hydrophilic polymer paint is formulated to counteract frost deposition on cold surfaces. The coated surface can retard frost formation up to three hours under low plate temperatures (-15.3°C) and high air humidity (72%). To test the antifrosting performance of the hydrophilic paint under more practical conditions, it is applied to a fin-and-tube heat exchanger and a domestic refrigerator at a coating thickness of 30 μm. Comparisons of frost deposition, pressure drops, and outlet temperatures are made between uncoated and coated heat exchangers. Under conditions of high air temperature (2.2°C) and relative high air humidity (90%), the paint prolongs the defrosting interval from 80 to 137 min. Experimental observations also show that the coated hydrophilic fins are free of frost deposition during the entire course of the test and that the coating has no significant additional thermal resistance.

关键词: frost formation     hydrophilicity     heat and mass transfer     performance    

Grafting of PEG400 onto the surface of LLDPE/SMA film

CHEN Gufeng, ZHANG Yi, XU Jiarui, ZHU Yafei

《化学科学与工程前沿(英文)》 2007年 第1卷 第2期   页码 128-131 doi: 10.1007/s11705-007-0024-6

摘要: Linear low-density polyethylene (LLDPE) was melt and blended with styrene-maleic anhydride copolymer (SMA). The blending films were then immersed in poly(ethylene glycol)400 (PEG400) at room temperature. The surface composition of the blend films was determined by Fourier transform infra-red spectroscopy coupled with a variable incidence angle attenuated total reflection accessory (ATR-FTIR). Results show that PEG400 can be grafted onto the surface of the films via esterification with SMA. The immersion of PEG promotes the enrichment of SMA onto the surface of the films. The water contact angle data show that grafting of PEG400 onto PE can greatly improve the hydrophilicity of the PE surface. These experiments show that surface functionalization of polyethylene films by blending SMA and then surface grafting of PEG is feasible, which suggest an effective and simple route for PE surface modification via blending and grafting.

关键词: hydrophilicity     temperature     effective     immersion     reflection accessory    

Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

SUI Pengzhe, WEN Xianghua, HUANG Xia

《环境科学与工程前沿(英文)》 2007年 第1卷 第3期   页码 362-367 doi: 10.1007/s11783-007-0062-9

摘要: In this study, ultrasound was used to control the membrane fouling online in an anaerobic membrane bioreactor (AMBR). Short-term running experiments were carried out under different operating conditions to explore feasible ultrasonic parameters. The experimental results indicated that when the crossflow velocity was more than 1.0 m/s, membrane fouling could be controlled effectively only by hydrodynamic methods without ultrasound. When ultrasound was applied, an ultrasonic power range of 60–150 W was suitable for the membrane fouling control in the experimental system. The experimental results showed that the membrane fouling was controlled so well that membrane filtration resistance (Σ) could stay at 5 × 10 m for more than a week with the crossflow velocity of 0.75 m/s, which equaled the effect of crossflow velocity of more than 1.0 m/s without ultrasound.

关键词: membrane filtration     filtration resistance     different     feasible ultrasonic     anaerobic membrane    

Novel membrane separation technologies and membrane processes

Yanying Wei, Gongping Liu, Jianquan Luo, Libo Li, Zhi Xu

《化学科学与工程前沿(英文)》 2021年 第15卷 第4期   页码 717-719 doi: 10.1007/s11705-021-2053-y

A critical review on thermodynamic mechanisms of membrane fouling in membrane-based water treatment process

《环境科学与工程前沿(英文)》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1729-6

摘要:

● Fundamentals of membrane fouling are comprehensively reviewed.

关键词: Membrane fouling     Thermodynamic mechanism     XDLVO theory     Flory-Huggins theory     Fouling migration    

A review on membrane distillation in process engineering: design and exergy equations, materials and

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 592-613 doi: 10.1007/s11705-021-2105-3

摘要: One of the problems that most afflicts humanity is the lack of clean water. Water stress, which is the pressure on the quantity and quality of water resources, exists in many places throughout the World. Desalination represents a valid solution to the scarcity of fresh water and several technologies are already well applied and successful (such as reverse osmosis), producing about 100 million m3·d−1 of fresh water. Further advances in the field of desalination can be provided by innovative processes such as membrane distillation. The latter is of particular interest for the treatment of waste currents from conventional desalination processes (for example the retentate of reverse osmosis) as it allows to desalt highly concentrated currents as it is not limited by concentration polarization phenomena. New perspectives have enhanced research activities and allowed a deeper understanding of mass and heat transport phenomena, membrane wetting, polarization phenomena and have encouraged the use of materials particularly suitable for membrane distillation applications. This work summarizes recent developments in the field of membrane distillation, studies for module length optimization, commercial membrane modules developed, recent patents and advancement of membrane material.

关键词: membrane distillation     recent developments     heat and mass transfer     wetting     membrane material    

Pilot plants of membrane technology in industry: Challenges and key learnings

Colin A. Scholes

《化学科学与工程前沿(英文)》 2020年 第14卷 第3期   页码 305-316 doi: 10.1007/s11705-019-1860-x

摘要: Membrane technology holds great potential in gas separation applications, especially carbon dioxide capture from industrial processes. To achieve this potential, the outputs from global research endeavours into membrane technologies must be trialled in industrial processes, which requires membrane-based pilot plants. These pilot plants are critical to the commercialization of membrane technology, be it as gas separation membranes or membrane gas-solvent contactors, as failure at the pilot plant level may delay the development of the technology for decades. Here, the author reports on his experience of operating membrane-based pilot plants for gas separation and contactor configurations as part of three industrial carbon capture initiatives: the Mulgrave project, H3 project and Vales Point project. Specifically, the challenges of developing and operating membrane pilot plants are presented, as well as the key learnings on how to successfully manage membrane pilot plants to achieve desired performance outcomes. The purpose is to assist membrane technologists in the carbon capture field to achieve successful outcomes for their technology innovations.

关键词: membrane gas separation     membrane contactors     carbon capture     pilot plants     key learnings    

Membrane bioreactors for hospital wastewater treatment: recent advancements in membranes and processes

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 634-660 doi: 10.1007/s11705-021-2107-1

摘要: Discharged hospital wastewater contains various pathogenic microorganisms, antibiotic groups, toxic organic compounds, radioactive elements, and ionic pollutants. These contaminants harm the environment and human health causing the spread of disease. Thus, effective treatment of hospital wastewater is an urgent task for sustainable development. Membranes, with controllable porous and nonporous structures, have been rapidly developed for molecular separations. In particular, membrane bioreactor (MBR) technology demonstrated high removal efficiency toward organic compounds and low waste sludge production. To further enhance the separation efficiency and achieve material recovery from hospital waste streams, novel concepts of MBRs and their applications are rapidly evolved through hybridizing novel membranes (non hydrophilic ultrafiltration/microfiltration) into the MBR units (hybrid MBRs) or the MBR as a pretreatment step and integrating other membrane processes as subsequent secondary purification step (integrated MBR-membrane systems). However, there is a lack of reviews on the latest advancement in MBR technologies for hospital wastewater treatment, and analysis on its major challenges and future trends. This review started with an overview of main pollutants in common hospital wastewater, followed by an understanding on the key performance indicators/criteria in MBR membranes (i.e., solute selectivity) and processes (e.g., fouling). Then, an in-depth analysis was provided into the recent development of hybrid MBR and integrated MBR-membrane system concepts, and applications correlated with wastewater sources, with a particular focus on hospital wastewaters. It is anticipated that this review will shed light on the knowledge gaps in the field, highlighting the potential contribution of hybrid MBRs and integrated MBR-membrane systems toward global epidemic prevention.

关键词: membrane technology     membrane bioreactor     hospital wastewater     hybrid MBR     integrated MBR-membrane system    

Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1606-1615 doi: 10.1007/s11705-022-2200-0

摘要: The increasing applications of seawater desalination technology have led to the wide usage of polyamide reverse osmosis membranes, resulting in a large number of wasted reverse osmosis membranes. In this work, the base nonwoven layer of the wasted reverse osmosis membrane was successfully modified into the hydrophobic membrane via surface deposition strategy including TiO2 and 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS), respectively. Various techniques were applied to characterize the obtained membranes, which were then used to separate the oil–water system. The optimally modified membrane displayed good hydrophobicity with a contact angle of 135.2° ± 0.3°, and its oil–water separation performance was as high as 97.8%. After 20 recycle tests, the oil–water separation performance remained more than 96%, which was attributed to the film adhesion of the anchored TiO2 and PFOTS layer on the surface. This work might provide a new avenue for recycling the wasted reverse osmosis membrane used in oily wastewater purification.

关键词: oil–water separation     wasted reverse osmosis membrane     hydrophobic modification    

Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobicceramic membrane bioreactor

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

《环境科学与工程前沿(英文)》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1131-6

摘要:

The existence of three-phase separator did not affect COD removal in the EAnCMBR.

The existence of three-phase separator aggravated methane leakage of EAnCMBR.

The existence of three-phase separator aggravated membrane fouling rate of EAnCMBR.

Start-up of EAnCMBR equipped three-phase separator was slightly delayed.

关键词: Anaerobic membrane bioreactor     Three-phase separator     Membrane fouling     Methane leakage     Sludge property    

Recent advances in membrane bioreactor technology for wastewater treatment in China

Xia HUANG, Kang XIAO, Yuexiao SHEN

《环境科学与工程前沿(英文)》 2010年 第4卷 第3期   页码 245-271 doi: 10.1007/s11783-010-0240-z

摘要: Since the introduction of the membrane bioreactor (MBR) in China in the early 1990s, remarkable progress has been achieved on the research and application of this technology. China has now become one of the most active fields in the world in this regard. This review outlines the development of MBR-based processes in China and their performance of treating municipal and industrial wastewaters. Since membrane fouling is a critical operational problem with MBR processes, this paper also proposes updated understanding of fouling mechanisms and strategies of fouling control, which are mainly compiled from publications of Chinese researchers. As for the commercial application of MBR in the country, the latest statistics of large-scale MBR plants (>10000 m·d) are provided, and the growth trend of total treatment capacity as well as its driving force is analyzed.

关键词: membrane bioreactor (MBR)     municipal wastewater treatment     industrial wastewater treatment     membrane fouling     commercial application     China    

标题 作者 时间 类型 操作

Hydrophilic modification of poly(aryl sulfone) membrane materials toward highly-efficient environmental

期刊论文

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

期刊论文

氯化水与地表水导致的膜污染对比解析——生物污染特性和微生物探究

张莉, 徐磊, Nigel Graham, 俞文正

期刊论文

两亲高分子对超微滤膜的高性能化改性及应用

朱宝库,崔月,王俊,王纳川,姚之侃,朱利平

期刊论文

Experimental investigations of frost release by hydrophilic surfaces

Zhongliang LIU, Lingyan HUANG, Yujun GOU, Yaomin LIU

期刊论文

Grafting of PEG400 onto the surface of LLDPE/SMA film

CHEN Gufeng, ZHANG Yi, XU Jiarui, ZHU Yafei

期刊论文

Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

SUI Pengzhe, WEN Xianghua, HUANG Xia

期刊论文

Novel membrane separation technologies and membrane processes

Yanying Wei, Gongping Liu, Jianquan Luo, Libo Li, Zhi Xu

期刊论文

A critical review on thermodynamic mechanisms of membrane fouling in membrane-based water treatment process

期刊论文

A review on membrane distillation in process engineering: design and exergy equations, materials and

期刊论文

Pilot plants of membrane technology in industry: Challenges and key learnings

Colin A. Scholes

期刊论文

Membrane bioreactors for hospital wastewater treatment: recent advancements in membranes and processes

期刊论文

Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

期刊论文

Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobicceramic membrane bioreactor

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

期刊论文

Recent advances in membrane bioreactor technology for wastewater treatment in China

Xia HUANG, Kang XIAO, Yuexiao SHEN

期刊论文